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Silica, which be drawn into fibers at reasonably high temperatures, has a fairly broad glass transformation range. One other advantage is that fusion splicing and cleaving of silica fibers is relatively effective. Silica fiber also has high mechanical strength against both pulling and even bending, provided that the fiber is not too thick and that the surfaces have been well prepared during processing. Even simple cleaving (breaking) of the ends of the fiber can provide nicely flat surfaces with acceptable optical quality. Silica is also relatively chemically inert. In particular, it is not hygroscopic (does not absorb water) also it can be doped with various materials. Silica fiber also exhibits a high threshold for optical damage. But, pure silca is not best suitable for optical fiber, because it exhibits a low solubility for rare earth ions. This can lead to quenching effects due to clustering of dopant ions. These properties makes silca most widely use material for optical fibers.
Process
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Today Three methods are used to manufacture optical fiber.
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Modified Chemical Vapor Deposition
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First, a cylindrical preform is made by depositing layers of specially formulated silicon dioxide on the inside surface of a hollow substrate rod. The layers are deposited by applying a gaseous stream of pure oxygen to the substrate rod. Various chemical vapors, such as silicon tetrachloride (SiCl 4 ), germanium tetrachloride (GeCl 4 ), and phosphorous oxychloride (POC1 3 ), are added to the stream of oxygen. As the oxygen contacts the hot surface of the rod--a flame underneath the rod keeps the walls of the rod very hot--silicon dioxide of high purity is formed. The result is a glassy soot, several layers thick, deposited inside the rod. This soot will become the core. The properties of these layers of soot can be altered depending on the types of chemical vapors used.
After sufficient layers are built up, the tube is collapsed into a solid glass rod referred to as a preform. It is now a scale model of the desired fiber, but much shorter and thicker. The preform is then taken to the drawing tower, where it is pulled into a length of fiber up to 10 kilometers long.
Refrences
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http://www.thefoa.org/tech/fibr-mfg.html
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