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Dispersion

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The refractive index of materials varies with the wavelength (and frequency) of light. This is called dispersion and causes prisms to divide white light into its constituent spectral colors, and explains how rainbows are formed. As the refractive index varies with wavelength, according to Snell's law, so will the refraction angle as light goes from one material to another. This makes different colors go in different directions.
In optics, *dispersion* is the phenomenon in which the phase velocity of a wave depends on its frequency,^\[1\]^ or alternatively when the group velocity depends on the frequency. The *refractive index* of materials varies with the wavelength (and frequency) of light.
Media having such a property are termed _dispersive media_. Dispersion is sometimes called *{_}chromatic{_}{*}* dispersion* to emphasize its wavelength-dependent nature, or *group-velocity dispersion* (*GVD*) to emphasize the role of the group velocity.
Dispersion is most often described for&nbsp;light&nbsp;waves, but it may occur for any kind of wave that interacts with a medium or passes through an inhomogeneous geometry (e.g., a&nbsp;[<span style="color: #0b0080">waveguide</span>|http://en.wikipedia.org/wiki/Waveguide]), such as&nbsp;sound&nbsp;waves
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Fig 01: A&nbsp;dispersive prism, material dispersion (a&nbsp;[<span style="color: #0b0080">wavelength</span>|http://en.wikipedia.org/wiki/Wavelength]\-dependent [<span style="color: #0b0080">refractive index</span>|http://en.wikipedia.org/wiki/Refractive_index]) causes different colors to [<span style="color: #0b0080">refract</span>|http://en.wikipedia.org/wiki/Refraction]&nbsp;at different angles, splitting white light into a&nbsp;[<span style="color: #0b0080">rainbow</span>|http://en.wikipedia.org/wiki/Rainbow].

Refractive index 

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(light)

A single ray of light consist of seven different color with varying wavelength. When a ray of light travels from one transparent medium to another(e.g from air to glass) then it splits into its constituent color (Red,Orange,Yellow,Green,Blue,Indigo,Violet). This phenomenon by which a ray of light  slits into its constituent color when it is passed through a transparent medium is called dispersion. Refraction is the cause and dispersion is the result. 

 
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Understanding Chromatic Dispersion with analogy

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urlhttp://www.youtube.com/watch?v=PWaNMjimtP0

Fig 01: A dispersive prism, material dispersion (a wavelength-dependent refractive index) causes different colors to refract at different angles, splitting white light into a rainbow
    Source : Wikipedia dispersion  

Refractive index

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The refractive index (or index of refraction) of a medium is a measure for how much the speed of light (or other waves such as sound waves) is reduced inside the medium. For example, typical glass has a refractive index of 1.5, which means that in glass, light travels at 1 / 1.5 = 0.67 times the speed of light in a vacuum. Two common properties of glass and other transparent materials are directly related to their refractive index. First, light rays change direction when they cross the interface from air to the material, an effect that is used in lenses and glasses. Second, light reflects partially from surfaces that have a refractive index different from that of their surroundings.Definition: The refractive index n of a medium is defined as the ratio of the phase velocity c of a wave phenomenon such as light or sound in a reference medium to the phase velocity vp in the medium itself:n = c / vp

Simply, it is the Specific property of medium to propagate or refract light or radiation.

Chromatic Aberration 

In Optics, chromatic aberration (CA, also called achromatism or chromatic distortion) is a type of distortion in which there is a failure of a lens to focus all colors to the same convergence point. It occurs because lenses have a different refractive index for different wavelengths of light (the dispersion of the lens). The refractive index decreases with increasing wavelength.
In simple, it is condition in which the lens fails to focus all colors at conversing point due to Dispersion Of the lens.

Fig 02: Showing effect of aberration on photography and correction with use of wide angle Lens

Source:Wikipedia Chromatic aberration



Mathematical analysis of Dispersion of light
A material's dispersion is measured by its Abbe numberV, with low Abbe numbers corresponding to strong dispersion. For optics in the visual range the amount of dispersion of a lens material is often quantified by the Abbe number  .

References

1) Aggarwala K, Kruger PB, Mathews S. et al Spectral Bandwidth and Ocular Accommodation. Journal of the Optical Society of America, 1995, 12, p 450

2)  Isaac Newton: adventurer in thought, by Alfred Rupert Hall, page 67